Which Skye Blue are you looking for?  I found about 12 different women named Skye Blue... 4 are "porn stars" and 5 are "escorts", and several with pornhub or similar sites that are neither porn stars (as I would define the term) or escorts (as far as I can tell from their video sites).

Was in a recent episode of Tonight's Girlfriend

I think it's the same girl as the one in the link below on IAFD.  If you follow the links from that page to her other pages, I think you'll see it's her but with a different hairdo and a bit younger.  Also, if you follow the links, you'll find an email address where you can contact her.  I'm not sure about the rules here these days about posting personal email addresses or links to certain sites so I'm refraining from doing so since I don't want to get "busted" the first week back. LOL!  

Anyway, you con contact her via email but be careful.  You might not be talking directly to her but to an agent or someone she's hired to handle the emails.  Or that address may be purely for booking her for shoots.

FWIW, I haven't seen her listed by any of the agencies that I've dealt with and can't find any case of her advertising that she's available as an escort so I'm inclined to think that the answer is "no" but, maybe... you never know.  

Hope this helps.