One on one, while I don't mind trying all sorts of positions, invariably, my favorite is missionary, occasionally with the ladies legs up on my shoulders for deeper penetration. Not very exciting, but it's what I like.
If you want to talk about involving multiple people... Here are a few favs...
Guy laying on his back with 2 girls sitting, facing each other. Once sitting on his dick and one sitting on his face.
A guy (or girl) fucking someone doggie style. That person is getting fucked either by a guy, or a girl with a strap-on (depending on orientation or preference). Optionally, add as many people as possible in a chain.
And, of course, an old favorite party game... Tied down, spread eagled, and blindfolded, with no idea who is fucking, or sucking, or sitting on your face, or doing whatever. Optionally, with a quiz afterwards on who did what and in what order